It doesn't really matter. You can learn how to use Linux from any Linux distro. The question is if you want to force yourself to learn how to use Linux to duplicate a Windows-like environment, or if you just want a Windows-like environment to feel comfortable and just learn when you feel like it.
Mine GO BOOM - Sun Sep 05, 2004 12:26 am
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Do you want to use this as a replacement for your main machine, or as a secondary computer? If secondary, I'd recommend Gentoo. Very good one to learn with, as long as you don't plan on using that as your main machine for a week or so until you get used to it.